Optimizing solid electrolyte interphase on graphite anode by adjusting the electrolyte solution structure with ionic liquid

Optimizing solid electrolyte interphase on graphite anode by adjusting the electrolyte solution structure with ionic liquid

TitleOptimizing solid electrolyte interphase on graphite anode by adjusting the electrolyte solution structure with ionic liquid
Publication TypeJournal Article
Year of Publication2018
AuthorsXimei Gao, Yuanlei Ding, Qunting Qu, Gao Liu, Vincent S Battaglia, Honghe Zheng
JournalElectrochimica Acta
Volume260
Pagination640 - 647
Date Published01/2018
ISSN00134686
Abstract

N-allyl-N-methylpiperidinium bis(trifuoromethansulfonyl)imide (PP13*TFSI) ionic liquid was adopted as a solute replacing partial of lithium salt in a concentrated propylene carbonate (PC) electrolyte. Varying the concentration of PP13*TFSI ionic liquid can change the electrolyte solution structure and thus optimize the solid electrolyte interphase (SEI) on the graphite anode. The number of PC molecules coordinated with lithium ion is significantly altered and this results in a change of the SEI mechanism at the electrode/electrolyte interface. At an optimum molar ratio of 2:1 between LiTFSI and PP13*TFSI, the first coulombic efficiency and the cycling capability of the graphite anode are significantly improved. Fourier transform infrared spectroscopy (FTIR) verified the SEI mechanism change from two-electron reduction to one-electron reduction in the presence of PP13*TFSI ionic liquid. SEM and TEM observations reveal a thin, homogenous and compact SEI film formed on the graphite surface in the 3 mol L−1 LiTFSI+PP13*TFSI(2:1)/PC concentrated electrolyte.

DOI10.1016/j.electacta.2017.12.009
Short TitleElectrochimica Acta
Refereed DesignationRefereed