All-climate sodium ion batteries based on the NASICON electrode materials

All-climate sodium ion batteries based on the NASICON electrode materials

TitleAll-climate sodium ion batteries based on the NASICON electrode materials
Publication TypeJournal Article
Year of Publication2016
AuthorsTiefeng Liu, Bo Wang, Xingxing Gu, Lei Wang, Min Ling, Gao Liu, Dianlong Wang, Shanqing Zhang
JournalNano Energy
Volume30
Pagination756 - 761
Date Published01/2016
ISSN22112855
Abstract

In this work, we have achieved all-climate high-rate performance of sodium ion batteries by utilizing electrode materials with Na Super Ionic Conductor (NASICON) crystalline structure. A designed NASICON-structured carbon-coated Na3V2(PO4)3 ([email protected]) nanocomposite exhibits an excellent performance at high rates in a wide temperature range (i.e., from −20 to 55 °C). Even at a low temperature of −20 °C, the [email protected] cathode can still maintain a discharge capacity of 91.3 mA h g−1 or 85.2% of the room performance at 10C, and secure an average output voltage of 2.86 V (vs. Na+/Na). These excellent wide-temperature accomplishments can be ascribed to fast three-dimensional Na+ hopping transportation mechanism in the NASICON structure. The finding in this work offers a promising strategy to address the long-standing inherent wide-temperature issues of rechargeable batteries and extends the potential application of sodium ion batteries.

DOI10.1016/j.nanoen.2016.09.024
Short TitleNano Energy
Refereed DesignationRefereed