Achieving Fast and Durable Lithium Storage through Amorphous FeP Nanoparticles Encapsulated in Ultrathin 3D P-Doped Porous Carbon Nanosheets

Achieving Fast and Durable Lithium Storage through Amorphous FeP Nanoparticles Encapsulated in Ultrathin 3D P-Doped Porous Carbon Nanosheets

TitleAchieving Fast and Durable Lithium Storage through Amorphous FeP Nanoparticles Encapsulated in Ultrathin 3D P-Doped Porous Carbon Nanosheets
Publication TypeJournal Article
Year of Publication2020
AuthorsZhiming Zheng, Hong-Hui Wu, Haodong Liu, Qiaobao Zhang, Xin He, Sicen Yu, Victoria Petrova, Jun Feng, Robert Kostecki, Ping Liu, Dong-Liang Peng, Meilin Liu, Ming-Sheng Wang
JournalACS Nano
Volume14
Issue8
Pagination9545 - 9561
Date Published07/2020
ISSN1936-0851
Abstract

Conversion-type transition-metal phosphide anode materials with high theoretical capacity usually suffer from low-rate capability and severe capacity decay, which are mainly caused by their inferior electronic conductivities and large volumetric variations together with the poor reversibility of discharge product (Li3P), impeding their practical applications. Herein, guided by density functional theory calculations, these obstacles are simultaneously mitigated by confining amorphous FeP nanoparticles into ultrathin 3D interconnected P-doped porous carbon nanosheets (denoted as [email protected]via a facile approach, forming an intriguing 3D flake-CNs-like configuration. As an anode for lithium-ion batteries (LIBs), the resulting [email protected] electrode not only reaches a high reversible capacity (837 mA h g–1 after 300 cycles at 0.2 A g–1) and an exceptional rate capability (403 mA h g–1 at 16 A g–1) but also exhibits extraordinary durability (2500 cycles, 563 mA h g–1 at 4 A g–1, 98% capacity retention). By combining DFT calculations, in situ transmission electron microscopy, and a suite of ex situ microscopic and spectroscopic techniques, we show that the superior performances of [email protected] anode originate from its prominent structural and compositional merits, which render fast electron/ion-transport kinetics and abundant active sites (amorphous FeP nanoparticles and structural defects in P-doped CNs) for charge storage, promote the reversibility of conversion reactions, and buffer the volume variations while preventing pulverization/aggregation of FeP during cycling, thus enabling a high rate and highly durable lithium storage. Furthermore, a full cell composed of the prelithiated [email protected] anode and commercial LiFePO4 cathode exhibits impressive rate performance while maintaining superior cycling stability. This work fundamentally and experimentally presents a facile and effective structural engineering strategy for markedly improving the performance of conversion-type anodes for advanced LIBs.

DOI10.1021/acsnano.9b08575
Short TitleACS Nano
Refereed DesignationRefereed